Writing on Superhydrophobic Nanopost Arrays: Topographic Design for Bottom-up Assembly

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Original Entry by Ryan Truby

AP 225 - Introduction to Soft Matter

November 10, 2012

Reference Information

Authors: B. D. Hatton, J. Aizenberg

Citation: B. D. Hatton and J. Aizenberg. Writing on Superhydrophobic Nanopost Arrays: Topographic Design for Bottom-up Assembly. Nano Lett. 2012, 12, 4551-4557.

Related Course Keywords: wetting, superhydrophobicity

Background and Introduction

Fig. 1, reproduced from [1]

In the Aizenberg Biomineralization and Biomimetics Lab at Harvard, researchers have fabricated arrays of vertical, nanoscale silicon posts to create i) novel actuating surfaces that serve as sensor and stimuli-response surfaces, ii) freeze-resistant surfaces, as well as iii) patterned substrates for studying bacterial assembly and cell mechanics. The nanopost arrays are created via a Bosch process, a method of deep reactive-ion etching, in silicon wafers that yields vertical nanoposts of tunable densities, aspect ratios, and cross-sectional areas. The Aizenberg Lab has also found that the same nanopost arrays demonstrate intriguing wetting properties. When in contact with water, the nanopost arrays cause water to bead-up on the nanoposts' highest surfaces, such that no water enters the space between the nanoposts or comes in contact with any portion of the nanoposts' vertical surfaces.

The field of soft matter physics has a general interest in the formation, stability, dynamics, and wettability of thin films of liquids. In fact, numerous studies reported over several decades have attempted to describe the enhanced hydrophobic characteristics observed on surfaces that specifically exhibit non-uniform topologies, such as rough and porous surfaces. Thus, understanding the superhydrophobicity of the nanopost arrays fabricated and studied in Professor Aizenberg's lab presents an interesting lesson in soft matter physics.

In the paper presented here, the authors demonstrate the superhydrophobic properties of silicon nanopost arrays and exploit them to assemble and pattern colloidal materials and polymers. Given below are a summary of this work, a physical explanation of the superhydrophobicity phenomenon observed with the nanopost arrays, as well as a discussion on the relevance of this work to the field of soft matter physics.

Summary

Fig. 2, reproduced from [1]
Fig. 3, reproduced from [1]
Fig. 4, reproduced from [1]

Discussion and Relevance to Soft Matter

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References

[1] B. D. Hatton and J. Aizenberg. Writing on Superhydrophobic Nanopost Arrays: Topographic Design for Bottom-up Assembly. Nano Lett. 2012, 12, 4551-4557.