Difference between revisions of "Surfactant"

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== Keyword in references: ==
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[[Modeling Surfactant Adsorption on Hydrophobic Surfaces]]
[[Amphiphilic Crescent-Moon-Shaped Microparticles Formed by Selective Adsorption of Colloids]]
[[Amphiphilic Crescent-Moon-Shaped Microparticles Formed by Selective Adsorption of Colloids]]
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[[Surface roughness directed self-assembly of patchy particles into colloidal micelles]]
[[Surface roughness directed self-assembly of patchy particles into colloidal micelles]]
[[Modeling Surfactant Adsorption on Hydrophobic Surfaces]]

Revision as of 06:02, 27 November 2012

Entry by Haifei Zhang, AP 225, Fall 2009

What is surfactant

A micelle—the lipophilic tails of the surfactant molecules remain on the inside of the micelle due to unfavourable interactions.

Surfactant is a combination of three words: Surface Active Agents. Surfactants are wetting agents that lower the surface tension of a liquid, allowing easier spreading, and lower the interfacial tension between two liquids. Surfactants are usually organic compounds that are amphiphilic, meaning they contain both hydrophobic groups (their "tails") and hydrophilic groups (their "heads"). Therefore, they are soluble in both organic solvents and water.

As shown in the figure on right, the polar "heads" of the micelle, due to favourable interactions with water, form a hydrophilic outer layer that in effect protects the hydrophobic core of the micelle. The compounds that make up a micelle are typically amphiphilic in nature, meaning that not only are micelles soluble in protic solvents such as water but also in aprotic solvents as a reverse micelle


Surfactants reduce the surface tension of water by adsorbing at the liquid-gas interface. They also reduce the interfacial tension between oil and water by adsorbing at the liquid-liquid interface. Many surfactants can also assemble in the bulk solution into aggregates. Examples of such aggregates are vesicles and micelles. The concentration at which surfactants begin to form micelles is known as the critical micelle concentration or CMC. When micelles form in water, their tails form a core that can encapsulate an oil droplet, and their (ionic/polar) heads form an outer shell that maintains favorable contact with water. When surfactants assemble in oil, the aggregate is referred to as a reverse micelle. In a reverse micelle, the heads are in the core and the tails maintain favorable contact with oil. Surfactants are also often classified into four primary groups; anionic, cationic, non-ionic, and zwitterionic (dual charge). Thermodynamics of the surfactant systems are of great importance, theoretically and practically. This is because surfactant systems represent systems between ordered and disordered states of matter. Surfactant solutions may contain an ordered phase (micelles) and a disordered phase (free surfactant molecules and/or ions in the solution). Ordinary washing up (dishwashing) detergent, for example, will promote water penetration in soil, but the effect would only last a few days (many standard laundry detergent powders contain levels of chemicals such as sodium and boron, which can be damaging to plants and should not be applied to soils). Commercial soil wetting agents will continue to work for a considerable period, but they will eventually be degraded by soil micro-organisms. Some can, however, interfere with the life-cycles of some aquatic organisms, so care should be taken to prevent run-off of these products into streams, and excess product should not be washed down.


Many applications

Surfactants play an important role in many practical applications and products, including:

  • Detergents
  • Fabric softener
  • Emulsifiers and Emulsions
  • Paints
  • Adhesives
  • Inks
  • Anti-fogging
  • Soil remediation
  • Dispersants
  • Wetting
  • Ski wax, snowboard wax
  • Deinking of recycled paper, both in flotation, washing and enzymatic processes
  • Foaming agents
  • Defoamers
  • Laxatives
  • Agrochemical formulations
    • Herbicides some
    • Insecticides
  • Quantum dot coating
  • Biocides (sanitizers)
  • Shampoo
  • Hair conditioners (after shampoo)
  • Spermicide (nonoxynol-9)
  • Firefighting
  • Pipeline, Liquid drag reducing agent
  • Alkali Surfactant Polymers (used to mobilize oil in oil wells)
  • Ferrofluids
  • Leak Detectors


Schematic Sketch of Surfactant Molecule
Schematic Sketch of Surfactant Molecules in Water

A particular type of molecular structure performs as a surfactant. This molecule is made up of a water soluble (hydrophilic) and a water insoluble (hydrophobic) component. The hydrophobe is usually the equivalent of an 8 to 18 carbon hydrocarbon, and can be aliphatic, aromatic, or a mixture of both. The sources of hydrophobes are normally natural fats and oils, petroleum fractions, relatively short synthetic polymers, or relatively high molecular weight synthetic alcohols. The hydrophilic groups give the primary classification to surfactants, and are anionic, cationic and nonionic in nature. The anionic hydrophiles are the carboxylates (soaps), sulphates, sulphonates and phosphates. The cationic hydrophiles are some form of an amine product. The nonionic hydrophiles associate with water at the ether oxygens of a polyethylene glycol chain. In each case, the hydrophilic end of the surfactant is strongly attracted to the water molecules and the force of attraction between the hydrophobe and water is only slight. As a result, the surfactant molecules align themselves at the surface and internally so that the hydrophile end is toward the water and the hydrophobe is squeezed away from the water.

Because of this characteristic behaviour of surfactants to orient at surfaces and to form micelles, all surfactants perform certain basic functions. However, each surfactant excels in certain functions and has others in which it is deficient.

Foaming agents, emulsifiers, and dispersants are surfactants which suspend respectively, a gas, an immiscible liquid, or a solid in water or some other liquid. Although there is similarity in these functions, in practice the surfactants required to perform these functions differ widely. In emulsification, as an example - the selection of surfactant or surfactant system will depend on the materials to be used and the properties desired in the end product. An emulsion can be either oil droplets suspended in water, an oil in water (O/W) emulsion, water suspended in a continuous oil phase, water in oil (W/O) emulsion, or a mixed emulsion. Selection of surfactants, orders of addition and relative amounts of the two phases determine the class of emulsion.

Each of these three functions is related to the surfactant absorbing at a surface, either gas, liquid or solid with the hydrophilic ends of the molecules oriented to the water phase. The surfactants form what amounts to a protective coating around the suspended material, and these hydrophilic ends associate with the neighbouring water molecules. In addition to surfactant effects the stability of these suspensions is related to the particle size and density of the suspended material.

Simplified Illustration of Detergency

Solubilisation is a function closely related to emulsification. As the size of the emulsified droplet becomes smaller, a condition is reached where this droplet and the surfactant micelle are the same size.

At this stage, an oil droplet can be imagined as being in solution in the hydrophobic tails of the surfactant and the term solubilisation is used. Emulsions are milky in appearance and solubilised oils, for example - are clear to the eye.

The function of detergency or cleaning is a complex combination of all the previous functions. The surface to be cleaned and the soil to be removed must initially be wet and the soils suspended, solubilised, dissolved or separated in some way so that the soil will not just re-deposit on the surface in question


[1] http://en.wikipedia.org/wiki/Surfactant

[2] http://www.chemistry.co.nz/surfactants.htm

[3] The Science of Chocolate: interactive activities on phase transitions, emulsification, and nucleation

Keyword in references:

Amphiphilic Crescent-Moon-Shaped Microparticles Formed by Selective Adsorption of Colloids

Biomimetic Morphogenesis of Calcium Carbonate in Mixed Solutions of Surfactants and Double-Hydrophilic Block Copolymers

Krafft Points, Critical Micelle Concentrations, Surface Tension, and Solubilizing Power of Aqueous Solutions of Fluorinated Surfactants

Order–disorder transition induced by surfactant micelles in single-walled carbon nanotubes dispersions

Patterned Colloidal Coating Using Adhesive Emulsions

Reversible aggregation of responsive polymer-stabilized colloids and the pH-dependent formation of porous scaffolds

Enriching libraries of high-aspect-ratio micro- or nanostructures by rapid, low-cost, benchtop nanofabrication

Liquid-infused structured surfaces with exceptional anti-biofouling performance

Liquid-Infused Nanostructured Surfaces with Extreme Anti-Ice and Anti-Frost Performance

Dynamics of foam drainage

Dynamic mechanisms for apparent slip on hydrophobic surfaces

Phase diagrams for sonoluminescing bubbles

Non-coalescence of oppositely charged droplets in pH-sensitive emulsions

Yielding and Flow of Monodisperse Emulsions

Swollen Vesicles and Multiple Emulsions from Block Copolymers

Spontaneous Formation of Lipid Structures at Oil/Water/Lipid Interfaces

Production of Unilamellar Vesicles Using an Inverted Emulsion

Short-time self-diffusion of nearly hard spheres at an oil–water interface

Hierarchical Porous Materials Made by Drying Complex Suspensions

Double Emulsion Droplets as Microreactors for Synthesis of Mesoporous Hydroxyapatite

Microfluidic Fabrication of Monodisperse Biocompatible and Biodegradable Polymersomes with Controlled Permeability

Droplet Microfluidics for Fabrication of Non-Spherical Particles

Arrested Coalescence of Particle-coated Droplets into Nonspherical Supracolloidal Structures

Early development drug formulation on a chip: Fabrication of nanoparticles using a microfluidic spray dryer

Fabrication of Monodisperse Toroidal Particles by Polymer Solidification in Microfluidics

Asymmetric functionalization of colloidal dimer particles with gold nanoparticles

Single-bubble sonoluminescence

Four-phase merging in sessile compound drops

Elasticity of an interfacial particle raft

Dynamics of Surfactant-Driven Fracture of Particle Rafts

Mechanics of Interfacial Composite Materials

Gravitational Stability of Suspensions of Attractive Colloidal Particles

Elastohydrodynamics of wet bristles, carpets and brushes

Shock-driven jamming and periodic fracture of particulate rafts

Colloidal spheres confined by liquid droplets: Geometry, physics, and physical chemistry

Measuring Dynamics and Interactions of Colloidal Particles with Digital Holographic Microscopy

Self-Assembly of Polyhedral Hybrid Colloidal Particles

Surfactant-Assisted Synthesis of Uniform Titania Microspheres and Their Clusters

Microtubule Protofilament Number Is Modulated in a Stepwise Fashion by the Charge Density of an Enveloping Layer

Cationic liposome–microtubule complexes: Pathways to the formation of two-state lipid–protein nanotubes with open or closed ends

Fluctuations in membranes with crystalline and hexatic order

Biomimetic Isotropic Nanostructures for Structural Coloration

Comparison of low-amplitude oscillatory shear in experimental and computational studies of model foams

Short-range order and near-field effects on optical scattering and structural coloration

Stable island arrays by height-constrained Stranski–Krastanov growth

Nanoscale Domain Stability in Organic Monolayers on Metals

New directions in mechanics

Measuring the elastic modulus of microgels using microdrops

Surface Energy as a Barrier to Creasing of Elastomer Films: An Elastic Analogy to Classical Nucleation

Novel Colloidal Interactions in Anisotropic Fluids

Surfactant-Mediated Two-Dimensional Crystallization of Colloidal Crystals

High-throughput injection with microfluidics using picoinjectors

Air-bubble-triggered drop formation in microfluidics

Syringe-vacuum microfluidics: A portable technique to create monodisperse emulsions

Monodisperse Gas-Filled Microparticles from Reactions in Double Emulsions

Universal non-diffusive slow dynamics in aging soft matter


Patterned Colloidal Coating Using Adhesive Emulsions

Inverted and multiple nematic emulsions

Osmotic pressure and viscoelastic shear moduli of concentrated emulsions

Micro!uidic fabrication of smart microgels from macromolecular precursors

Functionalized glass coating for PDMS microfluidic devices

Bacillus subtilis spreads by surfing on waves of surfactant

Structure of adhesive emulsions

Droplet-Based Microfluidics for Emulsion and Solvent Evaporation Synthesis of Monodisperse Mesoporous Silica Microspheres

Rheology of attractive emulsions

Colloidosomes: Selectively Permeable Capsules Composed of Colloidal Particles

Interactions between surfactant-coated surfaces in hydrocarbon liquids containing functionalized polymer dispersant

Self-Assembled Polymer Membrane Capsules Inflated by Osmotic Pressure

Rheology of Binary Colloidal Structures Assembled via Specific Biological Cross-Linking

Biocompatible surfactants for water-in-fluorocarbon emulsions

Self-assembled Shells Composed of Colloidal Particles: Fabrication and Characterization

Amphiphilic Crescent-Moon-Shaped Microparticles Formed by Selective Adsorption of Colloids

Colloid Surfactants for Emulsion Stabilization

Synthesis of Nonspherical Colloidal Particles with Anisotropic Properties

Gravitational Stability of Suspensions of Attractive Colloidal Particles

Surface roughness directed self-assembly of patchy particles into colloidal micelles

Modeling Surfactant Adsorption on Hydrophobic Surfaces