Difference between revisions of "Self-organization of a mesoscale bristle into ordered hierarchical helical assemblies"

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Edited by Qichao Hu
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September 13th, 2010
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reference: [http://www.sciencemag.org/cgi/content/abstract/sci;323/5911/237?maxtoshow=&hits=10&RESULTFORMAT=&andorexacttitleabs=and&andorexactfulltext=and&searchid=1&FIRSTINDEX=0&volume=323&firstpage=237&resourcetype=HWCIT]
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A well known phenomenon is the clumping of wet hair.  
 
A well known phenomenon is the clumping of wet hair.  
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[[Image:Wet_hair.jpg]]  
 
[[Image:Wet_hair.jpg]]  
  
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<math>E</math>: Yong's modulus
 
<math>E</math>: Yong's modulus
  
<math>B\sim Er^4</math>: bending stiffness of the nano-pillars
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<math>B\simeq Er^4</math>: bending stiffness of the nano-pillars
  
 
<math>J</math>: adhesive energy per unit area
 
<math>J</math>: adhesive energy per unit area
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<math>\gamma</math>: interfacial tension of the evaporating liquid
 
<math>\gamma</math>: interfacial tension of the evaporating liquid
  
There is a competition between the capillary force due to the menisci that wants to pull the free ends of adjacent nano-pillars together, and the force due to the bending stiffness of the nano-pillars that wants to pull them apart and return to the straight position. These forces are related to the above parameters through the following:
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There is a competition between the capillary force due to the menisci (formed when the liquid evaporates to the level of the free ends) that wants to pull the free ends of adjacent nano-pillars together, and the force due to the stiffness of the nano-pillars that wants to resist the bending and return to the straight position. These forces are related to the above parameters through the following:
  
Bending force: <math>F_B\sim Bd/L^3</math>
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Bending force: <math>F_B\simeq Bd/L^3</math>
  
Capillary force: <math>F_C\sim \gamma r</math>
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Capillary force: <math>F_C\simeq \gamma r</math>
  
 
when the two forces are equal to each other, we arrive at the critical length of the nano-pillars, given by
 
when the two forces are equal to each other, we arrive at the critical length of the nano-pillars, given by
  
critical nano-pillar length: <math>L_C \sim (Bd/\gamma r)^{1/3} \sim (Ed/\gamma)^{1/3}r</math>
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critical nano-pillar length: <math>L_C \simeq (Bd/\gamma r)^{1/3} \simeq (Ed/\gamma)^{1/3}r</math>
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At this critical length, when the adhesive energy per unit area is equal to the interfacial tension <math>J=\gamma</math>, we arrive at another important length
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<math>L_a\simeq(Ed/J)^{1/3}r</math>
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These critical lengths can be used to guide the design of nano-pillars where such bending is possible and maintained even after the liquid evaporates. The following image shows both the schematic and SEM images for nano-pillars of different lengths.
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[[Image:nanopillar_1.jpg|400px|]]
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Regime I: <math>L_a>L>L_C</math> the nano-pillars will come together as long as there is capillary force between them, but move apart after the liquid evaporates.
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Regime IIa: <math>L\geq L_a>L_C</math> the free ends of the nano-pillars will touch and remain together after the liquid evaporates.
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Regime IIb and IIc: <math>L\gg L_a</math> the bending stiffness of the nano-pillars succumbs to the adhesive force and the nano-pillars twist around each other.
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Regime III and IV: These chiral clusters interact with each other and form large-area chiral structures.
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Since the nano-pillars used are assumed to be circularly symmetric, the chirality of the clusters is random. Occasionally, any impurities in the nano-pillars such as asymmetry in the nano-pillar cross section or preferential direction in evaporation will lead to a particular orientation or handedness in the chirality.
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As Regime IV continues, the size of each cluster grows, and the number of clusters decreases.
  
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[[Image:nanopillar_3.jpg|400px|]]
  
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This hierarchical assembly represents the self-assembly process of small clusters grow into larger and higher-order structures.
  
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The randomness in the clusters can be controlled by either introducing nano-pillars with elliptical cross sections, changing the direction of evaporation, or pre-tilting the nano-pillars. This leads to a directional bending of the nano-pillars under capillary force and the formation of large area clusters with controlled chirality.
  
[[Image:Example.jpg]]
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Such technique can be used to self-assemble nano-pillars to large-area, complicated, and helical structures with controlled dimension and orientation. One application is in capture-and-release systems. This following image demonstrate the stable adhesion and trapping of a particle by the helical clusters.
  
<math>\tau=\pi</math>
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[[Image:nanopillar_5.jpg|400px|]]

Latest revision as of 03:52, 5 October 2010

Edited by Qichao Hu

September 13th, 2010


reference: [1]


A well known phenomenon is the clumping of wet hair.

Wet hair.jpg

This can be explained by studying the elasticity of each hair strand and the adhesion among the neighboring hair strands. When the hair strands are immersed in water, and the water is allowed to evaporate, capillary forces between the strands cause them to deform, adhere to each other, and form clumps.

This paper demonstrates that this elastocapillary force can be used to self-assemble stiff and upright nano-pillars to helical clusters and even coiled large-area structures. The fundamental theory involves the following parameters:

<math>r</math>: circular radius of the nano-pillars

<math>L</math>: length of nano-pillars

<math>d</math>: distance between adjacent nano-pillars

<math>E</math>: Yong's modulus

<math>B\simeq Er^4</math>: bending stiffness of the nano-pillars

<math>J</math>: adhesive energy per unit area

<math>\gamma</math>: interfacial tension of the evaporating liquid

There is a competition between the capillary force due to the menisci (formed when the liquid evaporates to the level of the free ends) that wants to pull the free ends of adjacent nano-pillars together, and the force due to the stiffness of the nano-pillars that wants to resist the bending and return to the straight position. These forces are related to the above parameters through the following:

Bending force: <math>F_B\simeq Bd/L^3</math>

Capillary force: <math>F_C\simeq \gamma r</math>

when the two forces are equal to each other, we arrive at the critical length of the nano-pillars, given by

critical nano-pillar length: <math>L_C \simeq (Bd/\gamma r)^{1/3} \simeq (Ed/\gamma)^{1/3}r</math>

At this critical length, when the adhesive energy per unit area is equal to the interfacial tension <math>J=\gamma</math>, we arrive at another important length

<math>L_a\simeq(Ed/J)^{1/3}r</math>

These critical lengths can be used to guide the design of nano-pillars where such bending is possible and maintained even after the liquid evaporates. The following image shows both the schematic and SEM images for nano-pillars of different lengths.

Nanopillar 1.jpg

Regime I: <math>L_a>L>L_C</math> the nano-pillars will come together as long as there is capillary force between them, but move apart after the liquid evaporates.

Regime IIa: <math>L\geq L_a>L_C</math> the free ends of the nano-pillars will touch and remain together after the liquid evaporates.

Regime IIb and IIc: <math>L\gg L_a</math> the bending stiffness of the nano-pillars succumbs to the adhesive force and the nano-pillars twist around each other.

Regime III and IV: These chiral clusters interact with each other and form large-area chiral structures.

Since the nano-pillars used are assumed to be circularly symmetric, the chirality of the clusters is random. Occasionally, any impurities in the nano-pillars such as asymmetry in the nano-pillar cross section or preferential direction in evaporation will lead to a particular orientation or handedness in the chirality.

As Regime IV continues, the size of each cluster grows, and the number of clusters decreases.

Nanopillar 3.jpg

This hierarchical assembly represents the self-assembly process of small clusters grow into larger and higher-order structures.

The randomness in the clusters can be controlled by either introducing nano-pillars with elliptical cross sections, changing the direction of evaporation, or pre-tilting the nano-pillars. This leads to a directional bending of the nano-pillars under capillary force and the formation of large area clusters with controlled chirality.

Such technique can be used to self-assemble nano-pillars to large-area, complicated, and helical structures with controlled dimension and orientation. One application is in capture-and-release systems. This following image demonstrate the stable adhesion and trapping of a particle by the helical clusters.

Nanopillar 5.jpg