Planarization of Substrate Topography by Spin Coating

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Planarization of Substrate Topography by Spin Coating

Authors: L. E. Stillwagon, R. G. Larson, and G. N. Taylor

J. Electrochem. Soc. 134, 8, 2030-2037

Soft matter keywords

Spin coating, thin films, capillarity, viscosity

By Alex Epstein

Abstract from the original paper

The results of a study of topographic substrate planarization with films applied by a spin-coating process are reported. It is shown that spin coating produces conformal film profiles over topographic gaps on the substrate that are wider than about 50 um and that leveling of these gaps can only occur after spinning ceases if the film is able to flow over large distances. A comparison of the major forces acting on the film leads to the conclusion that the flow is driven primarily by capillarity when the width of the gap is less than 5000 um. A theory is developed that relates the time required to level the gaps to their width and to the thickness and viscosity of the film. The results of experiments performed to test the theory are presented and discussed.

Soft matters

Brief background

Spin coating is a widely used technique for coating a flat substrate with a thin film of a liquid material. It is particularly used in the electronics industry, where integrated circuits are manufactured by a sequence of photolithographic steps. However, these processing steps often result in not-so-flat topography. Modern IC's feature interlevel interconnects that can extend microns upward. The empirical "Moore's Law" tells us that maximum transistor density has been doubling in new computing hardware every 18 months since the early 1970s. Now consider basic physics as it applies to photolithography: resolution or minimum linewidth (l) and depth of focus (d) are related to the exposure wavelength (<math>\lambda</math>) and the numerical aperture (NA) of the lens as follows.

 <math>l \propto \lambda/NA</math>
 <math>d \propto \lambda/(NA)^2</math>

To achieve higher and higher resolution, we can decrease exposure wavelength or increase the numerical aperture; but either approach also reduces the depth of field. Reduced depth of field means that the process is more sensitive to non-flat spin coat topography resulting from a complex multi-level substrate. This has been worked around by using multilayer resist schemes, in which a thick spin-coated bottom layer planarizes the substrate topography, and only a thin top layer is used for imaging. Early studies of planarization of substrate topography revealed definite limitations. One important limitation, which this paper explains, is that the planarizing range of spin coated films is limited to a distance of about 50 um.

Fig. 1 Drawing of the film profile over a gap when the centrifugal and capillary forces are exactly balanced.

Force analysis

The authors analyze the four major forces acting on a film during spin coating. Centrifugal, capillary, and gravitational forces all drive flow outward; viscosity, on the other hand, resists flow. After spinning is complete, only capillarity and gravity drive flow--and as we soon see, gravity can be neglected. The authors assume a Newtonian fluid (viscosity independent of shear rate) and assume no evaporation of the liquid occurs during spinning. They state that whether a spin coated layer is conformal (equal thickness everywhere) or planar (flat surface) is to first order determined by the balance of centrifugal force versus capillary and gravitational forces. With two sets of competing forces (ignoring viscosity for the moment), there must exist some transitional condition when they balance. This condition is shown in Fig. 1.

The capillary force is proportional to the surface tension of the liquid film and to the curvature of the air-film interface. Applying the Pythagorean Theorem in Fig. 1, we get

 <math>R^2 = \frac{w^2}{4}+(R-h)^2</math>
Fig. 2 Helical
Fig. 3 Helical
Fig. 4 Helical
Fig. 5 Helical
Fig. 6 Helical
Fig. 7 Helical
Fig. 8 Helical