On The Movement of Small Particles Suspended in Stationary Liquids Required By The Molecular-Kinetic Theory of Heat .

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Einstein's paper on diffusion can be found here: [1]

In this paper, Einstein uses the kinetic-molecular theory of heat to describe how "bodies of microscopically visible size suspended in liquids" move randomly through the medium

By entertaining the possibility that the motion he described in his paper is the same as "Brownian molecular motion", Einstein makes a significant contribution to the debate between classical thermodynamics and the kinetic-molecular theory of heat (which later developed into the field of statistical mechanics).

"If it is really possible to observe the motion to be discussed here, along with the laws it is expected to obey, then classical thermodynamics can no longer be viewed as strictly valid even for microscopically distinguishable spaces, and an exact determination of the real size of atoms becomes possible. Conversely, if the prediction of this motion were to be provided wrong, this fact would provide a weighty argument against the molecular-kinetic conception of heat"(Einstein, A.)

Context for This Article

In 1905 (when this paper was written), there was a controversy between two schools of thought:

Classical Thermodynamics:

-a model that provided an exact description of the behavior of macroscopic materials by treating them as a continuum (as opposed to a set of discrete particles) -a deterministic model - could be used to determine how a material would behave with a change in pressure or temperature (for example)

Molecular Kinetic Theory of Heat:

- Boltzmann and Maxwell had developed a model that eventually developed into statistical mechanics -model that described matter as the movement and interrelations of a large number of discrete particles (on the order of Avogadro's number) -a statistical model - views everything (pressure, temperature, etc) as a statistical quantity (Andelman, Diamant)


Einstein begins his paper by pointing out the discrepancy between classical thermodynamics and the molecular-kinetic theory of heat in predicting the osmotic pressure produced by small suspended bodies -according to the classical theory of thermodynamics - a small suspended particle would not exert osmotic pressure because "the 'free energy' of the system does not seem to depend on the position of the wall and of the suspended bodies"(Einstein, A.)

-but - according to the molecular-kinetic theory of heat - the only difference between a suspended particle and a dissolved particle is SIZE and therefore, a suspended body should produce the same osmotic pressure as an equal number of dissolved molecules

Einstein goes on to show that a suspended particle in a liquid behaves like a big atom in equilibrium with the liquid - the liquid itself is a collection of smaller particles, moving at random and colliding with one another and that the particles in suspension diffuse through the medium - colliding with the liquid particles

-Einstein showed that the "existence of osmotic pressure is a consequence of the molecular-kinetic theory of heat, and that, according to this theory, at great dilutions numerically equal quantities of dissolved molecules and suspended particles behave completely identical with regard to osmotic pressure"(Einstein, A.)

-Einstein showed that the movement of these suspended particles in the liquid fulfill a statistical law so that the distance the particle moves will increase as the square root of the time <math>xo=sqrt(6Dt)</math> (where D is the diffusion coefficient)

-Einstein showed that the movement of suspended particles is the function of a dynamic equilibrium between two opposing processes: a) a force acting on each individual suspended particle (which is a function of the particles' position) b) diffusion - which is the result of the random motion of the particles due to thermal molecular motion

-from the establishment of a and b in dynamic equilibrium - Einstein concluded that the coefficient of diffusion depends only on the coefficient of friction of the liquid and the size of the suspended particles (aside from universal constants and absolute temperature)


1. Einstein, A. "On the Movement of Small Particles Suspended in Stationary Liquids Required by the Molecular-Kinetic Theory of Heat", Annalen der Physik, 17, 1905, 549-560 2. Andelman, D., Diamant, H. "100 Years Since Einstein's Less Known Revolution: From the pollen dance to atoms and back"[2]