Mesoscale Self-Assembly: Capillary Bonds and Negative Menisci

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Zach Wissner-Gross (February 23, 2009)

Information

Mesoscale Self-Assembly: Capillary Bonds and Negative Menisci [1]

Ned Bowden, Scott R. J. Oliver, and George M. Whitesides

The Journal of Physical Chemistry B, 2000, 104 (12), 2714-2724

Softmatter Keywords

Capillary forces, self-assembly, menisci, capillary length

Summary

In their paper, Whitesides and coworkers float a layer of millimeter-sized PDMS [2] hexagons between perfluorodecalin (PFD) and water. They further pre-treat different edges of the hexagons, making them either hydrophilic (by oxidizing the edges with a plasma cleaner) or hydrophobic (by protecting the edges from oxidation with an additional cured layer of PDMS). By carefully agitating the solutions, the authors are able to induce self-assembly over the course of minutes to hours, and observe how structure varies with different patterns of hydrophobicity/hydrophilicity.

This article was written as a sister article to another publication [3]. In that paper, the authors used PDMS with a density of 1.05 g/cm<math>^3</math>, barely greater than than of water. Here, the authors load their PDMS hexagons with aluminum oxide to a density of 1.86 g/cm<math>^3</math>, just less than that of PFD. The authors spend much of the paper discussing the theoretical and experimental differences observed between these two setups (i.e., in which case hydrophilic or hydrophobic interactions dominate).