Difference between revisions of "Hydrophilic PDMS microchannels for high-throughput formation of oil-in-water microdroplets and water-in-oil-in-water double emulsions."

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[[Image:C004046K-1.jpg|300px|thumb|right|'''Fig.1 ''' (a) Schematic of the LbL surface modification of a PDMS microchannel. (b) Schematic of polyelectrolytes deposited on the channel wall. (c) Fluorescence micrograph of four microchannels modified with different solution sequences.]]
 
[[Image:C004046K-1.jpg|300px|thumb|right|'''Fig.1 ''' (a) Schematic of the LbL surface modification of a PDMS microchannel. (b) Schematic of polyelectrolytes deposited on the channel wall. (c) Fluorescence micrograph of four microchannels modified with different solution sequences.]]
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The LbL method is largely automated by pumping segments of poly(allylamine hydrochloride) (PAH) solution, poly-(sodium 4-styrenesulfonate) (PSS) and aqueous NaCl washing solution into the plasma-oxidized channel with a syringe, as is shown in Fig. 1. The polyelectrolytes attach to the surface of PDMS via electrostatic interactions.

Revision as of 03:20, 12 September 2011

Entry by Yuhang Jin, AP225 Fall 2011

Reference

Wolfgang-Andreas C. Bauer, Martin Fischlechner, Chris Abell and Wilhelm T. S. Huck, Lab Chip, 2010, 10, 1814.

Keywords

polyelectrolytes deposition, microdroplets, double emulsions, microfluidics

Introduction

The paper presents a method of layer-by-layer (LbL) deposition of polyelectrolytes to modify the surface wettability of PDMS-based microfluidic devices. The resulting coatings show stable hydrophylicity and hydrophobicity, and allow for high throughput generation of microdroplets or double emulsions.

This approach has several advantages over previously available ones: long-term stability, simple protocols and negligible distortion of channel dimension.

Results and discussion

Fig.1 (a) Schematic of the LbL surface modification of a PDMS microchannel. (b) Schematic of polyelectrolytes deposited on the channel wall. (c) Fluorescence micrograph of four microchannels modified with different solution sequences.

The LbL method is largely automated by pumping segments of poly(allylamine hydrochloride) (PAH) solution, poly-(sodium 4-styrenesulfonate) (PSS) and aqueous NaCl washing solution into the plasma-oxidized channel with a syringe, as is shown in Fig. 1. The polyelectrolytes attach to the surface of PDMS via electrostatic interactions.